A new cell for the study of in situ chemical reactions using X-ray absorption spectroscopy.

Details

Serval ID
serval:BIB_CC50D2291C55
Type
Article: article from journal or magazin.
Collection
Publications
Institution
Title
A new cell for the study of in situ chemical reactions using X-ray absorption spectroscopy.
Journal
Journal of Synchrotron Radiation
Author(s)
Longo A., Balerna A., d'Acapito F., D'Anca F., Giannici F., Liotta L.F., Pantaleo G., Martorana A.
ISSN
0909-0495
Publication state
Published
Issued date
07/2005
Peer-reviewed
Oui
Volume
12
Number
4
Pages
499-505
Language
english
Notes
Publication types: Evaluation Studies ; Journal Article
Abstract
An in situ cell for reductive and oxidative treatments at different temperatures that allows the possibility of recording data as a function of temperature has been designed and constructed for X-ray absorption experiments at the GILDA beamline BM08 of ESRF. The cell is linked to a mass quadrupole spectrometer providing control of the reaction gases and monitoring of the products. The apparatus allows measurements to be performed both in transmission and fluorescence geometry. The cell was tested by studying the CO oxidation reaction promoted by a Pt/ceria-zirconia-supported catalyst. The CO(2) yield is correlated with the structural results confirming the existence of a strong metal-support interaction between the Pt metal clusters and the ceria-zirconia support.
Keywords
Carbon Dioxide/analysis, Carbon Dioxide/chemistry, Catalysis, Flow Injection Analysis/instrumentation, Flow Injection Analysis/methods, Oxidation-Reduction, Oxygen/analysis, Oxygen/chemistry, Platinum/chemistry, Specimen Handling/instrumentation, Specimen Handling/methods, Spectrometry, X-Ray Emission/instrumentation, Spectrometry, X-Ray Emission/methods, Temperature, X-Ray Diffraction/instrumentation, X-Ray Diffraction/methods, Zirconium/chemistry
Pubmed
Web of science
Create date
25/01/2008 15:14
Last modification date
20/08/2019 15:47
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