Adopting a mixed method design, this paper explores the configuration and evolution of work values of 64 young adults in transition from education to employment. Qualitative analyses point out the existence of four categories of work values: interesting tasks, good relationships, self-fulfillment, and attractive work conditions. Quantitative analyses show that work values are questioned during the school-to-work transition, refined according to the experience of labor market integration, and partially different according to gender, education type, and the quality of the integration process. Consequently, career counseling should integrate a deeper understanding of what clients consider as important in their work lives.