Chemical profiling of different hashish seizures by gas chromatography-mass spectrometry and statistical methodology: a case report

Details

Serval ID
serval:BIB_12D49B063DC7
Type
Article: article from journal or magazin.
Collection
Publications
Institution
Title
Chemical profiling of different hashish seizures by gas chromatography-mass spectrometry and statistical methodology: a case report
Journal
Forensic Science International
Author(s)
Cadola L., Broséus J., Esseiva P.
ISSN
1872-6283
ISSN-L
0379-0738
Publication state
Published
Issued date
10/2013
Peer-reviewed
Oui
Volume
232
Number
1-3
Pages
e24-e27
Language
english
Abstract
Limited information is available regarding the methodology required to characterize hashish seizures for assessing the presence or the absence of a chemical link between two seizures. This casework report presents the methodology applied for assessing that two different police seizures were coming from the same block before this latter one was split.
The chemical signature was extracted using GC-MS analysis and the implemented methodology consists in a study of intra- and inter-variability distributions based on the measurement of the chemical profiles similarity using a number of hashish seizures and the calculation of the Pearson correlation coefficient. Different statistical scenarios (i.e., a combination of data pretreatment techniques and selection of target compounds) were tested to find the most discriminating one.
Seven compounds showing high discrimination capabilities were selected on which a specific statistical data pretreatment was applied. Based on the results, the statistical model built for comparing the hashish seizures leads to low error rates. Therefore, the implemented methodology is suitable for the chemical profiling of hashish seizures.
Keywords
Cannabis, Cannabis resin, Illicit drugs chemical profiling, Gas chromatography-mass spectrometry, Similarity measures
Create date
23/09/2013 13:40
Last modification date
20/08/2019 13:41
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