Complete Carbonylation of fac-

Details

Serval ID
serval:BIB_16803
Type
Article: article from journal or magazin.
Collection
Publications
Institution
Title
Complete Carbonylation of fac-
Journal
Angewandte Chemie
Author(s)
Aebischer N., Schibli R., Alberto R., Merbach A.E.
ISSN
1521-3773[electronic]
Publication state
Published
Issued date
2000
Volume
39
Number
1
Pages
254-256
Language
english
Abstract
The rate constant of ligand exchange on the complex fac-[(99)Tc(H(2)O)(3)(CO)(3)](+) was determined by means of (13)C, (17)O, and (99)Tc NMR spectroscopy under pressurized conditions in aqueous media. After keeping the sample under CO pressure for an extended period, the formation of [(99)Tc(CO)(6)](+) could unambiguously be detected in the (13)C and (99)Tc NMR spectra.
Pubmed
Web of science
Create date
19/11/2007 9:38
Last modification date
20/08/2019 12:46
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