Effect of shear on an onion texture.
Details
Serval ID
serval:BIB_BB1808FEF049
Type
Article: article from journal or magazin.
Collection
Publications
Institution
Title
Effect of shear on an onion texture.
Journal
European Physical Journal. E, Soft Matter
ISSN
1292-8941 (Print)
ISSN-L
1292-8941
Publication state
Published
Issued date
2007
Volume
24
Number
2
Pages
129-137
Language
english
Notes
Publication types: Journal Article Publication Status: ppublish
Abstract
Lamellar systems are self-assemblies of surfactant molecules forming planar bilayers separated by layers of solvent. At sufficiently high shear rates, they are known to form spherical objects often referred to as onions. In this paper, we are concerned with the effect of shear on those multi-lamellar vesicles. We measure solvent diffusion by nuclear magnetic resonance (NMR) using a method which is sensitive to the time dependence of mean-squared displacements. This method, combined with NMR velocimetry, allows us to infer onion structure as a function of shear rate, identifying different regimes in which local viscosity is related to the onion size. The role of slip is examined and the stress dependence of wall slip velocities is determined.
Keywords
Computer Simulation, Lipid Bilayers/chemistry, Liposomes/chemistry, Membrane Fluidity, Models, Chemical, Models, Molecular, Onions/chemistry, Phase Transition, Shear Strength, Surface Properties
Pubmed
Web of science
Create date
08/07/2013 9:22
Last modification date
20/08/2019 15:29